Carbamoyl radicals from Se-phenylselenocarbamates: Intramolecular additions to alkenes

被引：22

作者：

Rigby, JH ^{[1
]}

Danca, DM ^{[1
]}

Horner, JH ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 46期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(98)01830-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of 5 exo-trig cyclizations of carbamoyl radicals generated from readily available Se-phenylselenocarbamates is reported. Kinetic studies indicate that the rate constant of this cyclization exceeds 1x10(8)s(-1) in several cases. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：8413 / 8416

页数：4

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