Organoiodine(V) Reagents in Organic Synthesis

被引：274

作者：

Zhdankin, Viktor V. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 05期

基金：

美国国家科学基金会;

关键词：

O-IODOXYBENZOIC ACID; DESS-MARTIN PERIODINANE; HYPERVALENT IODINE REAGENTS; CP-MOLECULES CP-263,114; BAYLIS-HILLMAN ADDUCTS; RAY CRYSTAL-STRUCTURE; SUPPORTED IBX AMIDE; IN-SITU GENERATION; ONE-POT SYNTHESIS; 2-IODOXYBENZOIC ACID;

D O I：

10.1021/jo1024738

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organohypervalent iodine reagents have attracted significant recent interest as versatile and environmentally benign oxidants with numerous applications in organic synthesis. This Perspective summarizes synthetic applications of hypervalent iodine(V) reagents: 2-iodoxybenzoic acid (IBX), Dess-Martin periodinane (DMP), pseudocyclic iodylarenes, and their recyclable polymer-supported analogues. Recent advances in the development of new catalytic systems based on the generation of hypervalent iodine species in situ are also overviewed.

引用

页码：1185 / 1197

页数：13

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