Magnetic non-equivalence in phosphate esters. Solvent effects on the H-1 NMR spectrum of dibenzyl 2-pyridylphosphate

被引：1

作者：

Mentz, M

Modro, TA

Koch, KR

vanRooyen, PH

机构：

[1] UNIV PRETORIA,DEPT CHEM,CTR HETEROATOM CHEM,PRETORIA 0002,SOUTH AFRICA

[2] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1996年 / 380卷 / 1-2期

关键词：

NMR spectroscopy; solvent effect; phosphate ester;

D O I：

10.1016/0022-2860(95)09208-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Methylene protons of benzyl groups in dibenzyl 2-pyrridylphosphate show strong magnetic non-equivalence in CDCl3, while the effect is absent in benzene-d(6) solutions. The non-equivalence is explained by the intramolecular N --> P interactions leading to the ''quasi trigonal bipyramidal'' geometry of the substrate, observed in solid state, as determined by X-ray diffraction.

引用

页码：125 / 131

页数：7

共 15 条

[1] Magnetic non-equivalence in phosphate esters. Solvent effects on the 1H NMR spectrum of dibenzyl 2-pyridylphosphate
Journal of Molecular Structure, 1996, 380 (1-2):
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