Densities and viscosities of aqueous solutions of pyrrolidine and piperidine from (20 to 50) °C

被引:16
|
作者
Alvarez, E
Gómez-Díaz, D
La Rubia, D
Navaza, JM [1 ]
机构
[1] Univ Santiago de Compostela, ETSE, Dept Chem Engn, Santiago De Compostela, Spain
[2] Univ Vigo, ETSEI, Dept Chem Engn, Vigo, Spain
[3] Univ Jaen, Fac Expt Sci, Dept Chem Engn, Jaen, Spain
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关键词
D O I
10.1021/je050005h
中图分类号
O414.1 [热力学];
学科分类号
摘要
In the present paper, density and kinematic viscosity have been determined for aqueous solutions of two amines (pyrrolidine and piperidine) at (20, 30, 40, and 50) degrees C. The study of these mixtures has covered its complete composition range. Density shows the typical behavior of the composition and temperature's effect, but viscosity shows a maximum with an increased amine composition. A Redlich-Kister type equation was employed to fit the excess properties.
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页码:1829 / 1832
页数:4
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