Remote sensing of ground-level PM2.5 combining AOD and backscattering profile

The remote sensing of PM2.5 (particulate matter concentration with aerodynamic diameter d <= 2.5 mu m) mass concentration is mostly based on the measurements of AOD (aerosol optical depth) that is a common product of satellite and ground instruments which measure spectral radiance. The relationship between surface PM2.5 and column integrated AOD is found associated with vertical and size distribution of aerosols. In this study, a non-linear regression model combining AOD and near surface backscatter for estimation of PM2.5 is developed and tested based on 6 years ground measurements from HUBC (Howard University Beltsville Campus) facility. Overall, the non-linear model explains similar to 60% of the variability in hourly PM2.5. The RMSE (root-mean-square error) is similar to 5.83 mu g/m(3) with a corresponding average PM2.5 of 15.43 mu g/m(3). That is a big improvement to the linear model using AOD alone (similar to 40% of the variability, RMSE is similar to 7.14 mu g/m(3)). The ceilometer measured near surface backscatter is found to improve the estimation of PM2.5-AOD relationship the most compared to other factors, such as aerosol size indicator, surface temperature, relative humidity, wind speed and pressure especially when AOD is large (AOD >= 0.3). As aerosol size indicator, two Angstrom exponents are calculated by AOD at three wavelengths of 415, 500, 860 nm and are found also important to the PM2.5-AOD relationship. In addition to the HUBC site, the model is tested based on the 4 years (2012 to 2015) measurements from ARM SGP site and the nearest EPA site. The results also show the significant role of the ceilometer measured near surface backscatter on improving estimation of PM2.5. This study illustrated the potential of ceilometer on investigation of air pollution. With broad ceilometer network, ground-level particle concentrations can be better determined. (C) 2016 Elsevier Inc. All rights reserved.