A Delayed Coking Model Built Using the Structure-Oriented Lumping Method

被引:37
|
作者
Tian, Lida [1 ]
Shen, Benxian [1 ]
Liu, Jichang [1 ]
机构
[1] E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
关键词
KINETIC-MODEL; CRACKING; CHEMISTRY; MIXTURES;
D O I
10.1021/ef201570s
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A total of 7004 types of molecular lumps and 92 types of reaction rules were proposed to characterize the feedstock and describe the reaction behaviors of delayed coking. The reaction rate constants were estimated as equations of structure vectors. A reaction kinetic model has been built to predict the products distribution of delayed coking. The good prediction accuracy of the model has been proven by the comparison of calculation results and experimental results of delayed coking.
引用
收藏
页码:1715 / 1724
页数:10
相关论文
共 50 条
  • [1] Building and Application of Delayed Coking Structure-Oriented Lumping Model
    Tian, Lida
    Shen, Benxian
    Liu, Jichang
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (10) : 3923 - 3931
  • [2] Molecular-level reaction network in delayed coking process based on structure-oriented lumping
    Ye, Lei
    Liu, Jichang
    Xing, Biao
    Qin, Xinglong
    Yu, Wenxin
    Xie, Jinquan
    Hou, Lixin
    Wang, Hangzhou
    Ji, Ye
    Lu, Diannan
    CHEMICAL ENGINEERING SCIENCE, 2021, 246
  • [3] Building a Kinetic Model for Steam Cracking by the Method of Structure-Oriented Lumping
    Tian, Lida
    Wang, Jiming
    Shen, Benxian
    Liu, Jichang
    ENERGY & FUELS, 2010, 24 (08) : 4380 - 4386
  • [4] A kinetic model for in situ coking denitrification of heavy oil with high nitrogen content based on starch using a structure-oriented lumping method
    He, Zhongwen
    Xu, Hui
    Zhou, Changlu
    Xin, Zhong
    Liu, Jichang
    Shen, Benxian
    RSC ADVANCES, 2018, 8 (57): : 32707 - 32718
  • [5] A Kinetic Model for Catalytic Cracking of Vacuum Gas Oil Using a Structure-oriented Lumping Method
    Zhu, R.
    Shen, B.
    Liu, J.
    Chen, X.
    ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2012, 34 (22) : 2066 - 2072
  • [7] Structure-Oriented Lumping Method: An Effective Tool for Molecular Refining
    Wang, Mengfei
    Yang, Heping
    Wang, Juan
    Gu, Tao
    Zhong, Mei
    Dai, Zhenghua
    Li, Jian
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2023, 62 (33) : 12845 - 12854
  • [8] Extension of structure-oriented lumping to vacuum residua
    Jaffe, Stephhen
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [9] Extension of structure-oriented lumping to vacuum residua
    Jaffe, SB
    Freund, H
    Olmstead, WN
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (26) : 9840 - 9852
  • [10] Molecular kinetic model for catalytic pyrolysis of FCC gasoline by structure-oriented lumping
    Sun, Zhongchao
    Shan, Honghong
    Liu, Yibin
    Yang, Chaohe
    Li, Chunyi
    Huagong Xuebao/CIESC Journal, 2012, 63 (02): : 486 - 492