Synthesis and characterization of O-alkyl, O-cycloalkyl and O-aryl trithiophosphato derivatives of trimethyltin(IV) chloride and tributyltin(IV) chloride

被引：4

作者：

Tripathi, UN ^{[1
]}

Sharma, DK ^{[1
]}

机构：

[1] Vikram Univ, Sch Studies Chem, Ujjain 456010, Madhya Pradesh, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2005年 / 180卷 / 07期

关键词：

phosphorotrithioate; tin(IV);

D O I：

10.1080/104265090884210

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trimethyltin(IV)trithiophosphates [(RO)P(S)S-2][Sn(Me)(3)](2) and tributyl tin (I-V)trithiophosphates [(RO)P(S)S-2][Sn(Bu)(3)](2) (R=CH3, -C2H5, C3H7, -C3H7iso -C4H9n, -C4H9iso, -C4H5scc, -C5H11iso, C6H5) were prepared in methanolic solution of R3SnCl and dipotassium salt of trithiophosphates in 2:1 molor ratio. These newly synthesised derivatives have been characterized by elemental analysis, molecular weight measurements, IR, C-13, P-31 and Sn-119,NMR spectral studies. Coordination number of four suggested for tin(IV) in these derivatives.

引用

页码：1559 / 1568

页数：10

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