Effect of DMPA Content of Polyurethane Dispersion on Coating Properties

被引:36
|
作者
Manvi, Gururaj N. [1 ]
Jagtap, Ramanand N. [1 ]
机构
[1] NM Parekh Marg, Inst Chem Technol, Mumbai 400019, Maharashtra, India
关键词
Anionic waterborne polyurethane dispersion; gloss; isophorane diisocyanate; poly(neopentyl glycol adipate); stability; WATERBORNE POLYURETHANE; URETHANE ACRYLATES; EMULSIONS;
D O I
10.1080/01932690903269776
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polyurethane dispersions were synthesized from poly(neopentyl glycol adipate), isophorane diisocyanate (IPDI), and dimethylol propionic acid (DMPA) using conventional acetone process. Differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and particle size analysis were utilized to characterize the above-synthesized dispersion. The effect of DMPA contents were studied on glass transition temperature (Tg), particle size, stability, and gloss; as well as, the effect of pH on gloss and drying time was also studied. It was found that gloss was inversely proportional to particle size and pH.
引用
收藏
页码:1376 / 1382
页数:7
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