Substrate-directed diastereoselective hydroaminomethylation of methallylic alcohols

被引：39
|
作者：
Breit, B [1 ]
机构：
[1] Philipps Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 29期
关键词：
hydroformylation; catalysis; stereocontrol; asymmetric reactions; asymmetric synthesis;
D O I：
10.1016/S0040-4039(98)01038-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Substrate directed diastereoselective hydroaminomethylation of methallylic alcohols has been achieved with the aid of the substrate bound catalyst directing o-DPPB-group (o-DPPB = ortho-diphenylphosphanyl benzoate). The amines 3-7, 10, 11 have been obtained in fair to good yields in diastereomer ratios greater than or equal to 94:6 (syn : anti). (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码：5163 / 5166
页数：4
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