Controlled polymerizations using metal-organic frameworks

被引：74
|
作者：
Mochizuki, Shuto [1 ]
Kitao, Takashi [2 ,3 ]
Uemura, Takashi [2 ,3 ,4 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Univ Tokyo, Dept Adv Mat Sci, Grad Sch Frontier Sci, 5-1-5 Kashiwanoha, Kashiwa, Chiba 2778561, Japan
[3] Univ Tokyo, Dept Appl Chem, Grad Sch Engn, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan
[4] Japan Sci & Technol Agcy JST, CREST, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 84期
关键词：
STEREOSPECIFIC RADICAL POLYMERIZATION; RING-OPENING POLYMERIZATION; DEPENDENT CROSS-LINKING; COORDINATION POLYMER; VINYL MONOMERS; MOF; CATALYSTS; FABRICATION; CRYSTALS; TRANSFORMATION;
D O I：
10.1039/c8cc06415f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This short review focuses on recent developments in polymerization reactions using metal-organic frameworks (MOFs). MOFs are crystalline porous materials that are able to tune their frameworks, enabling their use as promising media for polymerization. The precise design of the MOF structure is key to controlling polymerizations, allowing for the regulation of not only primary but also higher-order structures.
引用
收藏
页码：11843 / 11856
页数：14
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