Two isomeric Au complexes of S-trithiane: One-dimensional polymer assembled through aurophilic interactions

被引：11

作者：

Yue, Cheng-Yang ^{[1
,2
]}

Chen, Wan-Dong ^{[1
]}

Jiang, Fei-Long ^{[2
]}

Feng, Rui ^{[2
]}

Hong, Mao-Chun ^{[2
]}

机构：

[1] Jining Univ, Dept Chem, Qufu 273155, Shandong, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 01期

关键词：

Supermolecule; Polymer; Gold(I); S-trithiane; Aurophilicity; Luminescence; CLOSED-SHELL ATTRACTION; CRYSTAL-STRUCTURE; GOLD(I); CHEMISTRY; BEHAVIOR; LIGANDS; DIMERS; STATE; AU(I);

D O I：

10.1016/j.inoche.2009.10.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two isomeric Au complexes, [Au(Stt)Cl](n) (1) and [Au(Stt)Cl](4n) (2) (Stt = S-trithiane), have been prepared and structurally and spectroscopically characterized. Each compound crystallizes as a unique form with aurophilic interactions between the linear and two-coordinated Au(I) cations. In complex 1, the Au(Stt)Cl molecules self-associate to form 1D nearly linear chains via equivalent aurophilic interactions, whereas the structure of complex 2 features 1D flexural chains composed of zigzag [Au(Stt)Cl](4) tetramers through varying aurophilic interactions. Emission spectra of both complexes at room temperature give strong red luminescence. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.

引用

页码：105 / 108

页数：4

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