Photodimerization of anthracene having dendritic substituent within the vaterite crystal of CaCO3

被引:17
|
作者
Takaguchi, Y [1 ]
Yanagimoto, Y [1 ]
Tajima, T [1 ]
Ohta, K [1 ]
Motoyoshiya, J [1 ]
Aoyama, H [1 ]
机构
[1] Shinshu Univ, Fac Text Sci & Technol, Nagano 3868567, Japan
关键词
D O I
10.1246/cl.2002.1102
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Crystallization of CaCO3 in the presence of poly(amidoamine) (PAMAM) dendron containing an anthryl group at the focal point and carboxylate groups at the external surface resulted in the formation of spherical vaterite crystals. Furthermore, photodimerization reaction of anthracene unit proceeded within the vaterite crystals upon irradiation.
引用
收藏
页码:1102 / 1103
页数:2
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