Green oxidant H2O2 as a hydrogen atom transfer reagent for visible light-mediated Minisci reaction

被引：43
|
作者：
Zhao, Hong [1 ]
Li, Zhenlong [1 ,2 ]
Jin, Jian [1 ]
机构：
[1] Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, CAS Key Lab Synthet Chem Nat Subst,Ctr Excellence, 345 Lingling Rd, Shanghai 200032, Peoples R China
[2] Shanghai Inst Technol, Sch Chem & Environm Engn, 120 Caobao Rd, Shanghai 200235, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2019年 / 43卷 / 32期
基金：
上海市自然科学基金;
关键词：
C-H ALKYLATION; LATE-STAGE FUNCTIONALIZATION; BOND FUNCTIONALIZATION; N-HETEROARENES; DECARBOXYLATIVE ALKYLATION; METHYLATION; ACIDS; DEPROTONATION; HETEROCYCLES; OXIDATIONS;
D O I：
10.1039/c9nj03106e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A visible light-mediated green protocol for metal-free oxidative coupling of heteroarenes and aliphatic C-H components has been achieved via a radical pathway. This cross-dehydrogenative coupling method features a broad scope of substrates. The green oxidant H2O2 is used as a hydrogen atom transfer reagent, which is environmentally benign, low cost, and atom economical.
引用
收藏
页码：12533 / 12537
页数：5
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