Nickel-catalyzed Amide Transformation via C-N Bond Cleavage

被引：0
|
作者：
Nishii, Yuji
机构：
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2016年 / 74卷 / 08期
关键词：
CROSS-COUPLING REACTION; KETONE SYNTHESIS; ORGANOBORON COMPOUNDS; CARBOXYLIC-ACIDS; ESTERS; ANHYDRIDES; ACTIVATION; COMPLEXES;
D O I：
10.5059/yukigoseikyokaishi.74.824
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acyl metal species generated from carboxylic acid derivatives upon treating with low valent transition-metal complexes have been utilized for various catalytic transformations. Recently, it was revealed that a catalyst system of Ni(0)/NHC (N-Heterocyclic Carbene) triggered amide C-N bond cleavage via oxidative addition to afford acyl nickel complexes. The obtained acyl species were further converted into the corresponding esters and ketones in catalytic manner. A proposed reaction mechanism and some synthetic applications are concisely summarized herein.
引用
收藏
页码：824 / 825
页数：2
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