On the origin of near-IR luminescence in Bi-doped materials (II). Subvalent monocation Bi+ and cluster Bi53+ luminescence in AlCl3/ZnCl2/BiCl3 chloride glass

被引：86

作者：

Romanov, Alexey N. ^{[1
,2
]}

Fattakhova, Zukhra T. ^{[3
]}

Veber, Alexander A. ^{[4
]}

Usovich, Olga V. ^{[5
]}

Haula, Elena V. ^{[3
]}

Korchak, Vladimir N. ^{[3
]}

Tsvetkov, Vladimir B. ^{[4
]}

Trusov, Lev A. ^{[5
]}

Kazin, Pavel E. ^{[5
]}

Sulimov, Vladimir B. ^{[1
,2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Ctr Res Comp, Moscow 119992, Russia

[2] Dimonta Ltd, Moscow 117186, Russia

[3] Russian Acad Sci, NN Semenov Inst Chem Phys, Moscow 119991, Russia

[4] Russian Acad Sci, AM Prokhorov Gen Phys Inst, Moscow 119991, Russia

[5] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

OPTICS EXPRESS | 2012年 / 20卷 / 07期

关键词：

MOLTEN BISMUTH TRIHALIDES; LOWER OXIDATION-STATES; BROAD-BAND EMISSION; INFRARED PHOTOLUMINESCENCE; CRYSTAL-STRUCTURE; BI-6(2+) POLYCATIONS; BI-2(4+) DUMBBELLS; DILUTE-SOLUTIONS; SPECTRA; METAL;

D O I：

10.1364/OE.20.007212

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Broadband NIR photoluminescence (from 1000 to 2500 nm) was observed from partially reduced AlCl3/ZnCl2/BiCl3 glass, containing subvalent bismuth species. The luminescence consists of three bands, assigned to Bi+, Bi-2(4+), and Bi-5(3+) ions. The physical and optical characteristics of these centers and possible contribution to NIR luminescence from bismuth-doped oxide glasses are discussed. (C) 2012 Optical Society of America

引用

页码：7212 / 7220

页数：9

共 2 条

[1] On the origin of near-IR luminescence in Bi-doped materials (I). Generation of low-valence bismuth species by Bi3+ and Bi0 synproportionation
Romanov, Alexey N.
Fattakhova, Zukhra T.
Zhigunov, Denis M.
Korchak, Vladimir N.
Sulimov, Vladimir B.
OPTICAL MATERIALS, 2011, 33 (04) : 631 - 634
[2] Origin of near-IR luminescence in Bi2O3-GeO2 and Bi2O3-SiO2 glasses: first-principle study
Sokolov, V. O.
Plotnichenko, V. G.
Dianov, E. M.
OPTICAL MATERIALS EXPRESS, 2015, 5 (01): : 163 - 168

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