Synthesis and characterisation of a bridging nitrido complex of titanium

被引：17
|
作者：
Carmalt, CJ
Mileham, JD
White, AJP
Williams, DJ
机构：
[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England
[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
来源：
NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 12期
关键词：
D O I：
10.1039/b008211m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Titanium tetrachloride reacts with hexamethyldisilazane in the presence of 3,5-dimethylpyridine (L) to form a bridging nitrido species, [{Ti(2)Cl(5)(L)(5)}(mu -N)], the structure of which has been established by X-ray crystallography.
引用
收藏
页码：929 / 930
页数：2
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