Thermodynamics and mechanism of metal-induced crystallization in immiscible alloy systems: Experiments and calculations on Al/a-Ge and Al/a-Si bilayers

被引:72
|
作者
Wang, Z. M. [1 ]
Wang, J. Y. [1 ]
Jeurgens, L. P. H. [1 ]
Mittemeijer, E. J. [1 ]
机构
[1] Max Planck Inst Met Res, D-70569 Stuttgart, Germany
关键词
D O I
10.1103/PhysRevB.77.045424
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The mechanism of metal-induced crystallization (MIC) in immiscible alloy systems has been explained on a unified thermodynamic basis. Interface thermodynamics has been shown to play a decisive role for the occurrence of MIC. The thermodynamic predictions agree excellently with the corresponding experimental observations obtained in this project for the Al/Ge and Al/Si layer systems, which show two distinctly different types of MIC behaviors. As a result, a model has been developed that rationalizes and predicts MIC processes in immiscible alloy systems.
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页数:15
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