Synthesis and characterization of polymers for nonlinear optical applications

被引：1

作者：

Boucher, V ^{[1
]}

Cardin, J ^{[1
]}

Leduc, D ^{[1
]}

Seveno, R ^{[1
]}

Le Ny, R ^{[1
]}

Gundel, HW ^{[1
]}

Boisrobert, C ^{[1
]}

Legoupy, S ^{[1
]}

Legros, F ^{[1
]}

Montembault, V ^{[1
]}

Odobel, F ^{[1
]}

Monnereau, C ^{[1
]}

Blart, E ^{[1
]}

Bosc, D ^{[1
]}

Goullet, A ^{[1
]}

Mevellec, JY ^{[1
]}

机构：

[1] Univ Nantes, LPIO, EA 3254, Nantes, France

来源：

ADVANCED ORGANIC AND INORGANIC OPTICAL MATERIALS | 2003年 / 5122卷

关键词：

polymer; chromophore; poling; orientation; cross-linking; electro-optic; thin film; integrated optics;

D O I：

10.1117/12.515725

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A difunctional NLO Azo-Dye chromophore has been synthesized and polymerization has been performed with a comonomer bearing a side-chain epoxy group. Deposition of the polymer on glass substrates was performed by spin-coating, resulting in uniform films up to 2 pm thickness. The orientation of the chromophore was performed under a "pin-to-plane" positive corona discharge followed by a heat-treatment in order to obtain reticulation of the films. Molecular orientation has been investigated using UV-Vis. and Raman spectroscopy. Poling of the films results in a decay of absorbance as well as in a blue shift of the spectrum. At the same time, the 1600 cm(-1) band disappears from the Raman spectra, indicating orientation of the chromophores. Cross-linking has been studied by FTIR and all-optical poling and showed an improved stability of the electro-optic thin films.

引用

页码：206 / 209

页数：4

共 50 条

[1] SYNTHESIS AND CHARACTERIZATION OF LIQUID-CRYSTALLINE POLYMERS FOR NONLINEAR OPTICAL APPLICATIONS
MCCULLOCH, IA
BAILEY, RT
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1991, 200 : 157 - 165
[2] Synthesis and characterization of maleic anhydride derived crosslinkable polymers for nonlinear optical applications
Sun, SSJ
Maaref, S
Alam, E
Saulter, J
Wyatt, S
Wang, YQ
Bahoura, M
Bonner, CE
LINEAR, NONLINEAR, AND POWER-LIMITING ORGANICS, 2000, 4106 : 177 - 185
[3] Synthesis and characterization of maleic anhydride derived crosslinkable polymers for nonlinear optical applications
Maaref, S.
Alam, E.
Saulter, J.
Wyatt, S.
Sun, S.
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 2000, 41 (01):
[4] Synthesis and characterization of some new coordination polymers for third order nonlinear optical applications
Bader, MM
Pham, PTT
ORGANIC NONLINEAR OPTICAL MATERIALS, 1999, 3796 : 178 - 182
[5] Synthesis and Characterization of Y-Type Polymers for Second-Order Nonlinear Optical Applications
Kolli, Balakrishna
Mishra, Sarada P.
Palai, Akshaya K.
Kanai, Tapan
Joshi, M. P.
Mohan, S. Raj
Dhami, T. S.
Kukreja, L. M.
Samui, A. B.
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (04) : 836 - 843
[6] POLYMERS FOR NONLINEAR OPTICAL APPLICATIONS
ULRICH, DR
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 189 : 3 - 38
[7] Design and synthesis of new functional polymers for nonlinear optical applications
Abbotto, A
Beverina, L
Chirico, G
Facchetti, A
Feauti, P
Pagani, GA
SYNTHETIC METALS, 2003, 139 (03) : 629 - 632
[8] Synthesis and characterization of thiazolylazo chromophore for nonlinear optical applications
Pan, QW
Zhang, ZY
Fang, CH
Shi, W
Gu, QT
Wu, XW
MATERIALS LETTERS, 2001, 50 (5-6) : 284 - 286
[9] Synthesis and characterization of an alkoxysilane dye for nonlinear optical applications
Cui, YJ
Wang, MQ
Chen, LJ
Qian, GD
DYES AND PIGMENTS, 2005, 65 (01) : 61 - 66
[10] Synthesis and characterization of new truxenones for Nonlinear optical applications
Sanguinet, Lionel
Williams, Jarrod C.
Yang, Zhiyong
Twieg, Robert J.
Mao, Guilin
Singer, Kenneth D.
Wiggers, Greg
Petschek, Rolfe G.
CHEMISTRY OF MATERIALS, 2006, 18 (18) : 4259 - 4269

← 1 2 3 4 5 →