Organophotoredox-Catalyzed Decarboxylative C(sp3)-O Bond Formation

被引：125
|
作者：
Shibutani, Shotaro [1 ]
Kodo, Taiga [1 ]
Takeda, Mitsutaka [1 ]
Nagao, Kazunori [1 ]
Tokunaga, Norihito [2 ]
Sasaki, Yusuke [2 ]
Ohmiya, Hirohisa [1 ]
机构：
[1] Kanazawa Univ, Kakuma Machi, Kanazawa, Ishikawa, Japan
[2] Takeda Pharmaceut Co Ltd, Fujisawa, Kanagawa, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 03期
关键词：
PHOTOREDOX CATALYSIS; ALKYL-HALIDES; VISIBLE-LIGHT; SECONDARY; COUPLINGS; RADICALS; SULFIDES; ALCOHOLS; DONORS; ARYL;
D O I：
10.1021/jacs.9b12335
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This manuscript reports a visible-light-mediated organosulfide catalysis that enables the decarboxylative coupling between simple aliphatic alcohol and tertiary or secondary alkyl carboxylic acid-derived redox active esters to produce a C(sp(3))-O-C(sp(3)) fragment. Results of the coupling using other heteroatom nucleophiles such as water, amides, and thiols are also described.
引用
收藏
页码：1211 / 1216
页数：6
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