Supramolecular surfactants derived from calixarenes

被引:17
|
作者
Garcia-Rio, Luis [1 ]
Basilio, Nuno [2 ]
机构
[1] Univ Santiago de Compostela, Ctr Singular Invest Quim Biol & Mat Mol CIQUS, Dept Quim Fis, Santiago De Compostela 15782, Spain
[2] Univ Nova Lisboa, Dept Quim, Fac Ciencias & Tecnol, LAQV REQUIMTE, P-2829516 Caparica, Portugal
关键词
Supramolecular chemistry; Supramolecular surfactant; Calixarene; Micelle; Vesicle; P-SULFONATOCALIXARENE; AMPHIPHILES; VESICLES; RELEASE; RESORCINARENE; AGGREGATION; RECOGNITION;
D O I
10.1016/j.cocis.2019.11.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Supramolecular surfactants self-aggregate via noncovalent interactions. The process is rapid and reversible which makes them potentially useful for the design of stimuli-responsive systems. Here we focus on host:guest interactions using calixarenes as molecular receptors. Calixarenes are an important family of molecular receptors because of their ease of preparation and post-modification. The calixarenes discussed here cannot self-aggregate, but when combined with an appropriate guest molecule readily self-associate. Different types of aggregates are obtained, e.g., micelles or vesicles, depending upon the structures of the calixarene and guest.
引用
收藏
页码:225 / 237
页数:13
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