Steric effect in regioselective hydrostannation of alkyl o-alkoxycinnamates with triphenyltin hydride

被引：0

作者：

Kalita, Pankaj ^{[1
]}

Deka, Dibakar Chandra ^{[2
]}

机构：

[1] Arya Vidyapeeth Coll, Dept Chem, Gauhati 781016, Assam, India

[2] Gauhati Univ, Dept Chem, Gauhati 781014, Assam, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2014年 / 91卷 / 07期

关键词：

Triphenyltin; hydrostannation; alkyl o-alkoxycinnamates; BONDS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triphenyltin hydride under radical condition reacts with alkyl o-alkoxycinnamates to give hydrostannated products, where the stannyl group enters at a-position. Again, with increase in the bulkiness of alkoxy group product yield is decreased.

引用

页码：1351 / 1353

页数：3

共 4 条

[1] Isopropyl-substituted o-benzoquinones and oxanthrenequinones. Effect of steric shielding of alkyl substituents on reactivity
Kocherova, T. N.
Druzhkov, N. O.
Shavyrin, A. S.
Arsenyev, M., V
Baranov, E., V
Kuropatov, V. A.
Cherkasov, V. K.
RUSSIAN CHEMICAL BULLETIN, 2021, 70 (05) : 916 - 924
[2] Isopropyl-substituted o-benzoquinones and oxanthrenequinones. Effect of steric shielding of alkyl substituents on reactivity
T. N. Kocherova
N. O. Druzhkov
A. S. Shavyrin
M. V. Arsenyev
E. V. Baranov
V. A. Kuropatov
V. K. Cherkasov
Russian Chemical Bulletin, 2021, 70 : 916 - 924
[3] A remarkable effect of C-O-C bond angle strain on the regioselective double nucleophilic substitution of the acetal group of tetraacetal tetraoxa-cages and a novel hydride rearrangement of tetraoxa-cages
Wu, HJ
Chern, JH
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (10): : 3208 - 3214
[4] Unique chlorine effect in regioselective one-pot synthesis of 1-alkyl-/allyl-3-(o-chlorobenzyl) uracils:: anti-HIV activity of selected uracil derivatives
Malik, Vaishalli
Singh, Palwinder
Kumar, Subodh
TETRAHEDRON, 2006, 62 (25) : 5944 - 5951

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