A Robust Ca-Based Microporous Metal-Organic Framework for Thermodynamic Separation of Hexane Isomers

被引：13

作者：

Li, Xingyu ^{[1
,2
]}

Lin, Yuhan ^{[2
]}

Yu, Liang ^{[2
]}

Zou, Jizhao ^{[1
]}

Wang, Hao ^{[2
]}

机构：

[1] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518060, Peoples R China

[2] Shenzhen Polytech, Hoffmann Inst Adv Mat, Shenzhen 518055, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年 / 61卷 / 34期

基金：

中国国家自然科学基金;

关键词：

3D Structure - Adsorptive separation - Alkane isomers - Hexane isomers - Highly stables - Metalorganic frameworks (MOFs) - Microporous metal organic frameworks - Petrochemical industry - Pore dimensions;

D O I：

10.1021/acs.inorgchem.2c01024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Adsorptive separation of alkane isomers, especially the efficient separation of mono-and dibranched alkanes, remains challenging in the petrochemical industry. We report here the discrimination of alkane isomers through a thermodynamically driven mechanism by a highly stable calcium-based metal-organic framework. This newly developed 3D structure is built on a tetracarboxylate linker, featuring 1D channels with optimal pore dimensions to discriminate alkane isomers.

引用

页码：13229 / 13233

页数：5

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