Recent Progress on Cu-Catalyzed Conjugate Silylation to Unsaturated Compounds

被引：3

作者：

Tang, Xiaoqi ^{[1
,2
]}

Xie, Libo ^{[2
]}

Chen, Yali ^{[1
]}

Tian, Ping ^{[2
]}

Lin, Guoqiang ^{[2
]}

机构：

[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 36卷 / 09期

基金：

中国国家自然科学基金;

关键词：

copper; unsaturated compounds; asymmetric; conjugate silylation; ALPHA-BETA-UNSATURATION; HECK-TYPE REACTION; ALPHA; BETA-UNSATURATED KETONES; ASYMMETRIC 1,4-DISILYLATION; PHENYLDIMETHYLSILYL GROUP; CARBONYL-COMPOUNDS; ORGANIC-SYNTHESIS; PROTECTING GROUP; BORONIC ESTERS; SILICON;

D O I：

10.6023/cjoc201605004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organosilicon compounds have a wide range of applications in organic synthesis. It can be readily converted to a series of functional compounds through a simple operation. In the recent years, copper-catalyzed conjugate silylation of unsaturated compounds has emerged as a novel synthetic tool to introduce a variety of organosilicon compounds. Herein, this research progress, especially the development in the asymmetric conjugate silylation is summarized.

引用

页码：2011 / 2023

页数：13

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