Phenyliodine diacetate-mediated oxidative cleavage of cyclobutanols leading to γ-hydroxy ketones

被引：19
|
作者：
Fujioka, Hiromichi [1 ]
Komatsu, Hideyuki [1 ]
Miyoshi, Akihito [1 ]
Murai, Kenichi [1 ]
Kita, Yasuyuki [2 ]
机构：
[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan
[2] Ritsumeikan Univ, Coll Pharmaceut Sci, Shiga 5258577, Japan
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 09期
关键词：
Cyclobutanol; Phenyliodine diacetate; Oxidation; gamma-Hydroxy ketone; HYPERVALENT IODINE OXIDATION; NUCLEOPHILIC-SUBSTITUTION; OPENING REACTION; RING; DERIVATIVES; REARRANGEMENT; ETHERS; ROUTE;
D O I：
10.1016/j.tetlet.2010.12.032
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxidative cleavage of cyclobutanols using PIDA, which leads to efficient entry of gamma-hydroxy ketones, is described. When using 2-substituted cyclobutanols, gamma-substituted gamma-hydroxy ketones are obtained through regioselective C-C bond cleavage. (C) 2010 Elsevier Ltd. All rights reserved.
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收藏
页码：973 / 975
页数：3
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