Continuous synthesis of ZIF-67 by a microchannel mixer: A recyclable approach

被引：20
|
作者：
Zhang, Meizhuo [1 ,2 ]
Yu, Zhiquan [1 ,2 ]
Sun, Zhichao [1 ,2 ]
Wang, Anjie [1 ,2 ]
Zhang, Jian [3 ]
Liu, Ying-Ya [1 ,2 ]
Wang, Yao [1 ,2 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Liaoning Key Lab Petrochem Technol & Equipment, Dalian 116012, Peoples R China
[3] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2021年 / 327卷
关键词：
Metal-organic framework; ZIF-67; Microfluidic; Zeolitic imidazole framework; Flow synthesis; METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; ROOM-TEMPERATURE SYNTHESIS; NANOPARTICLE SYNTHESIS; STRUCTURAL EVOLUTION; THERMAL-STABILITY; ADSORPTION; MOF; CO; FLEXIBILITY;
D O I：
10.1016/j.micromeso.2021.111423
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Microfluidic synthesis of a Zeolitic-Imidazole Framework ZIF-67 at ambient temperature and pressure is reported. With a metal/ligand/triethylamine (TEA) ratio of 1/4/4, ZIF-67 can be produced with a high space-time yield (STY) of 57000 kg m(-3) d(-1) and a production rate of 285 g h(-1) in ethanol. It can be produced with a similar STY in water solution as well. Given the importance of sustainable synthesis, the recycling process of the mother liquor was investigated. The mother liquor can be recycled 5 times with high yield and crystallinity in ethanol, but not applicable in water solution. The morphology and particle sizes of ZIF-67 can be regulated in a controlling manner in a water-ethanol mixed solvent. Moreover, the influence of TEA on the characteristic of the ZIF-67 structure was investigated in detail.
引用
收藏
页数：9
相关论文
共 50 条
  • [1] Highly Efficient and Recyclable ZIF-67 Catalyst for the Degradation of Tetracycline
    Hou, Wenxin
    Huang, Yu
    Liu, Xiang
    CATALYSIS LETTERS, 2020, 150 (10) : 3017 - 3022
  • [2] Highly Efficient and Recyclable ZIF-67 Catalyst for the Degradation of Tetracycline
    Wenxin Hou
    Yu Huang
    Xiang Liu
    Catalysis Letters, 2020, 150 : 3017 - 3022
  • [3] Polymer/ZIF-67 composite as an effective and recyclable nanocatalyst for Biginelli reaction
    Houshiar, Saman
    Rafiee, Zahra
    Grami, Majidreza
    APPLIED ORGANOMETALLIC CHEMISTRY, 2022, 36 (09)
  • [4] Immobilization of Xylanase into Zeolitic Imidazolate Framework-67 (ZIF-67) and Manganese-Doped ZIF-67 (Mn/ZIF-67): A Comparison Study
    Bakar, Busra
    Dik, Gamze
    Ulu, Ahmet
    Ates, Burhan
    TOPICS IN CATALYSIS, 2024, 67 (9-12) : 698 - 713
  • [5] Immobilization of Xylanase into Zeolitic Imidazolate Framework-67 (ZIF-67) and Manganese-Doped ZIF-67 (Mn/ZIF-67): A Comparison Study
    Büşra Bakar
    Gamze Dik
    Ahmet Ulu
    Burhan Ateş
    Topics in Catalysis, 2024, 67 : 698 - 713
  • [6] Controllable Synthesis and Structural Analysis of Nanohybrids with Gold Multipod Nanoparticle Cores and ZIF-67 Shells (GMN@ ZIF-67)
    Hien Duy Mai
    Van Cam Thi Le
    Thu Minh Thi Pham
    Ko, Jae-Hyeon
    Yoo, Hyojong
    CHEMNANOMAT, 2017, 3 (12): : 857 - 862
  • [7] ZIF-67 derivatives in electrocatalysis
    Gao, Guoliang
    Xiao, Chengzhi
    Zhang, Rongrong
    Chen, Wangwei
    Liu, Conghu
    Zhu, Guang
    Sun, Bowen
    Dai, Lei
    Cabot, Andreu
    Sun, Zixu
    COORDINATION CHEMISTRY REVIEWS, 2025, 523
  • [8] Ultra-Sonication of ZIF-67 Crystals Results in ZIF-67 Nano-Flakes
    Beyer, Sebastian
    Prinz, Carsten
    Schuermann, Robin
    Feldmann, Ines
    Zimathies, Annett
    Blocki, Anna M.
    Bald, Ilko
    Schneider, Rudolf J.
    Emmerling, Franziska
    CHEMISTRYSELECT, 2016, 1 (18): : 5905 - 5908
  • [9] Hydrothermal synthesis of zeolitic imidazolate framework-67 (ZIF-67) nanocrystals
    Qian, Junfeng
    Sun, Fuan
    Qin, Lizhen
    MATERIALS LETTERS, 2012, 82 : 220 - 223
  • [10] Advances and Perspectives in ZIF-67 Synthesis for Hydrogen Applications: A Review
    Singh, Aaush Bhardwaj
    Yadav, Manishkumar D.
    ENERGY & FUELS, 2025, 39 (10) : 4610 - 4647
12345