Synthesis and electroluminescent properties of new coumarin derivatives

被引:0
|
作者
Jung, Hyocheol [1 ]
Kang, Seokwoo [1 ]
Shin, Donghee [2 ]
Song, Gihyun [1 ]
Kay, Kwang-Yol [2 ,3 ]
Park, Jongwook [1 ]
机构
[1] Kyung Hee Univ, Dept Chem Enginnering, Suwon, South Korea
[2] G OLED Co Ltd, Seongshin Technopk, Suwon, South Korea
[3] Ajou Univ, Dept Mol Sci & Technol, Suwon 16499, South Korea
基金
新加坡国家研究基金会;
关键词
Blue Chromophore; coumarin; fluorescence; organic light-emitting diode; BLUE; TRANSISTORS; POLYMER; DIODES;
D O I
10.1080/09273948.2017.1338882
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
4-methyl-7-(10-(pyren-1-yl)anthracen-9-yl)-2H-chromen-2-one (PAC), 7,7'-(anthracene-9,10-diyl)bis(4- methyl-2H-chromen-2-one) (CAC), 7-Ant-hracen-9-yl-4-methyl-chromen-2-one (AC), and 7-(naphthalen-1-yl)-2H-chromen-2-one (NC) were synthesized through Suzuki aryl-aryl coupling reaction. Optical and electroluminescence (EL) properties were evaluated by UV-visible absorption, photoluminescence (PL) spectra, and EL devices. Synthesized compounds were used as an emitting layer (EML) in non-doped device with the following structures: ITO/2-TNATA (60nm)/NPB (15nm)/synthesized compounds (35nm)/Alq(3) (20nm)/LiF (1nm)/Al (200nm). Non-doped devices showed luminance efficiency (L.E.) of 1.38, 1.03, 1.12, and 0.39cd/A at a current density of 10mA/cm(2).
引用
收藏
页码:48 / 54
页数:7
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