We present analytical results for the structural evolution of random networks undergoing contraction processes via generic node deletion scenarios, namely, random deletion, preferential deletion, and propagating deletion. Focusing on configuration model networks, which exhibit a given degree distribution P-0 (k) and no correlations, we show using a rigorous argument that upon contraction the degree distributions of these networks converge towards a Poisson distribution. To this end, we use the relative entropy S-t = S[P-t (k)parallel to pi (k vertical bar < K >(t))] of the degree distribution P-t (k) of the contracting network at time t with respect to the corresponding Poisson distribution pi(k vertical bar < K >(t)) with the same mean degree < K >(t) as a distance measure between P-t (k) and Poisson. The relative entropy is suitable as a distance measure since it satisfies S-t >= 0 for any degree distribution P-t (k), while equality is obtained only for P-t (k) = pi (k vertical bar < K >(t)). We derive an equation for the time derivative dS(t)/dt during network contraction and show that the relative entropy decreases monotonically to zero during the contraction process. We thus conclude that the degree distributions of contracting configuration model networks converge towards a Poisson distribution. Since the contracting networks remain uncorrelated, this means that their structures converge towards an Erdos-Renyi (ER) graph structure, substantiating earlier results obtained using direct integration of the master equation and computer simulations [Tishby et al., Phys. Rev. E 100, 0 2314 (2019)]. We demonstrate the convergence for configuration model networks with degenerate degree distributions (random regular graphs), exponential degree distributions, and power-law degree distributions (scale-free networks).