Fabrication of Bi12O17Br2 with Efficient Photocatalytic N2 Fixation Boosted by Photoinduced Oxygen Vacancies

被引：2

作者：

Gao Mei-Chao ^{[1
]}

Gong Yun-Yun ^{[1
]}

Li Zi-Yue ^{[1
]}

Wang Bai-Hui ^{[1
]}

Huang Xiao-Qing ^{[1
]}

Yu Wen-Jiao ^{[1
]}

机构：

[1] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2022年 / 38卷 / 03期

关键词：

Bi12O17Br2; photocatalysis; oxygen vacancy; N-2 photo fixation; NITROGEN-FIXATION; BIOBR NANOSHEETS; CARBON NITRIDE; DEGRADATION; PHOTOREDUCTION; PERFORMANCE;

D O I：

10.11862/CJIC.2022.043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bi12O17Br2 photocatalyst was prepared through a one-pot hydrothermal method. An average microsheets size of 1.2 mu m and a high specific surface area of ca. 29 m(2).g(-1) were observed for Bi12O17Br2 photocatalyst. Bi12O17Br2 has a bandgap of 2.42 eV, which can be excited under visible light illumination. The photoinduced oxygen vacancies are easily generated on the surface of Bi12O17Br2. The N-2 molecules could be captured and activated by oxygen vacancies. An NH3 generation rate of 337.6 mu mol.g(-1).h(-1) was detected on Bi12O17Br2 under visible light irradiation. It demonstrates that the accomplishment of the visible-light-driven photocatalytic for the N-2 photo fixation with H2O over a Bi12O17Br2 photocatalyst.

引用

页码：542 / 550

页数：9

共 27 条

[1] In-situ approach to fabricate BiOI photocathode with oxygen vacancies: Understanding the N2 reduced behavior in photoelectrochemical system
Bai, Yajie
Bai, Hongye
Qu, Konggang
Wang, Fagen
Guan, Peng
Xu, Dongbo
Fan, Weiqiang
Shi, Weidong
[J]. CHEMICAL ENGINEERING JOURNAL, 2019, 362 : 349 - 356
[2] Electrochemical Reduction of N2 under Ambient Conditions for Artificial N2 Fixation and Renewable Energy Storage Using N2/NH3 Cycle
Bao, Di
Zhang, Qi
Meng, Fan-Lu
Zhong, Hai-Xia
Shi, Miao-Miao
Zhang, Yu
Yan, Jun-Min
Jiang, Qing
Zhang, Xin-Bo
[J]. ADVANCED MATERIALS, 2017, 29 (03)
[3] All-solid-state Z-scheme 3,4-dihydroxybenzaldehyde-functionalized Ga2O3/graphitic carbon nitride photocatalyst with aromatic rings as electron mediators for visible-light photocatalytic nitrogen fixation
Cao, Shihai
Zhou, Ning
Gao, Fenghua
Chen, Huan
Jiang, Fang
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 218 : 600 - 610
[4] Dai Y T, 2019, ANGEW CHEM INT EDIT, V539, P563
[5] Strain-Engineering of Bi12O17Br2 Nanotubes for Boosting Photocatalytic CO2 Reduction
Di, Jun
Song, Pin
Zhu, Chao
Chen, Chao
Xiong, Jun
Duan, Meilin
Long, Ran
Zhou, Weigiang
Xu, Manzhang
Kang, Lixing
Lin, Bo
Liu, Daobin
Chen, Shuangming
Liu, Chuntai
Li, Huaming
Zhao, Yanli
Li, Shuzhou
Yan, Qingyu
Song, Li
Liu, Zheng
[J]. ACS MATERIALS LETTERS, 2020, 2 (08): : 1025 - 1032
[6] Persian buttercup-like BiOBrxCl1-x solid solution for photocatalytic overall CO2 reduction to CO and O2
Gao, Meichao
Yang, Jinxiang
Sun, Tao
Zhang, Zizhong
Zhang, Dafeng
Huang, Huijuan
Lin, Huaxiang
Fang, Yi
Wang, Xuxu
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 243 : 734 - 740
[7] Facile hydrothermal synthesis of Bi/BiOBr composites with enhanced visible-light photocatalytic activities for the degradation of rhodamine B
Gao, Meichao
Zhang, Dafeng
Pu, Xipeng
Li, Hong
Lv, Dongdong
Zhang, Bingbing
Shao, Xin
[J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2015, 154 : 211 - 216
[8] Preparation and Photocatalytic Nitrogen Fixation Performance of Cd Doping δ-Bi2O3 Nanosheets
Gao Xiao-Ming
Shang Yan-Yan
Liu Li-Bo
Gao Kai-Long
[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2019, 35 (04) : 580 - 588
[9] Surprise in the phosphate modification of BiOCl with oxygen vacancy: In situ construction of hierarchical Z-scheme BiOCl-OV-BiPO4 photocatalyst for the degradation of carbamazepine
Gao, Xiaoya
Tang, Guangbei
Peng, Wen
Guo, Qian
Luo, Yongming
[J]. CHEMICAL ENGINEERING JOURNAL, 2019, 360 : 1320 - 1329
[10] Simultaneous generation of oxygen vacancies on ultrathin BiOBr nanosheets during visible-light-driven CO2 photoreduction evoked superior activity and long-term stability
Kong, Xin Ying
Ng, Boon-Junn
Tan, Kok Hong
Chen, Xiaofang
Wang, Huanting
Mohamed, Abdul Rahman
Chai, Siang-Piao
[J]. CATALYSIS TODAY, 2018, 314 : 20 - 27

← 1 2 3 →