A tetrazolate- and cyano-bridged homometallic mixed-valence copper(I,II) molecular ferrimagnet

被引：64
|
作者：
Zhang, Xian-Ming [1 ]
Zhao, Yan-Tei
Zhang, Wei-Xiong
Chen, Xiao-Ming
机构：
[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China
来源：
ADVANCED MATERIALS | 2007年 / 19卷 / 19期
关键词：
D O I：
10.1002/adma.200602410
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A solvothermal reaction of a cupric salt and tetrazole in acetonitrile generates a tetrazolate (tta)- and cyano-bridged homometallic mixed-valence copper(I,II) molecular ferrimagnet, [Cu(5)(tta)(6)(CN)(2)] (see figure), that exhibits a field-induced transition from a 3D antiferromagnetic state to a ferrimagnetic state at 7.9 K.
引用
收藏
页码：2843 / +
页数：5
相关论文
共 50 条
  • [1] Syntheses, crystal structures and magnetic properties of two cyano-bridged copper(I)-copper(II) mixed-valence complexes
    Jin, Yi
    Che, Yunxia
    Zheng, Jimin
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (06) : 691 - 698
  • [2] CHARACTERIZATION OF A MIXED-VALENCE CYANO-BRIDGED COBALT(III)IRON(II) COMPLEX
    BAGGER, S
    STOLTZE, P
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1983, 37 (03): : 247 - 250
  • [3] Architecture dependence on the steric constrains of the ligand in cyano-bridged copper(I) and Copper(II)-Copper(I) mixed-valence polymer compounds containing diamines:: Crystal structures and spectroscopic and magnetic properties
    Colacio, E
    Kivekas, R
    Lloret, F
    Sunberg, M
    Suarez-Varela, J
    Bardají, M
    Laguna, A
    INORGANIC CHEMISTRY, 2002, 41 (20) : 5141 - 5149
  • [4] Electroabsorption studies of charge transfer bands of cyano-bridged mixed-valence complexes.
    Karki, L
    Lu, H
    Hupp, JT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 426 - INOR
  • [5] Dinuclear cyano-bridged CoIII-FeII complexes as precursors for molecular mixed-valence complexes of higher nuclearity
    Bernhardt, PV
    Bozoglián, F
    González, G
    Martínez, M
    Macpherson, BP
    Sienra, B
    INORGANIC CHEMISTRY, 2006, 45 (01) : 74 - 82
  • [6] Two three-dimensional cyano-bridged bimetallic cadmium(II) and copper(II)-copper(I) mixed-valence polymer compounds: Crystal structures and thermal stability analysis and magnetic properties
    Jin, Yi
    Qi, Yan
    Batten, Stuart R.
    Cao, Pengzhen
    Chen, Wei
    Che, Yunxia
    Zheng, Jimin
    INORGANICA CHIMICA ACTA, 2009, 362 (10) : 3395 - 3400
  • [7] Cyano-bridged Homodinuclear Copper(II) Complexes
    Atanasov, Mihail
    Comba, Peter
    Hanson, Graeme R.
    Hausberg, Sascha
    Helmle, Stefan
    Wadepohl, Hubert
    INORGANIC CHEMISTRY, 2011, 50 (15) : 6890 - 6901
  • [8] Isolation and Properties of a Chain of Cyano-Bridged Complex {LCuII(μ-CN)}n With Triazenido Ligand and a Cyano-Bridged Mixed-Valence Complex {CuIICuI(μ-CN)3}n
    Jian, Wan-Yuan
    Li, Wei
    Lv, Qi-Ying
    Min, Xin
    Liu, Yue-Yun
    Zhan, Shu-Zhong
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (10) : 1375 - 1380
  • [9] ON A MIXED-VALENCE COPPER(I,II) COMPLEX WITH THIOVANOL
    NIGAM, HL
    KANTH, KM
    KRISHNA, V
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1980, 19 (08): : 804 - 805
  • [10] Molecular CoIII/FeII Cyano-Bridged Mixed-Valence Compounds with High Nuclearities and Diversity of CoIII Coordination Environments: Preparative and Mechanistic Aspects
    Bernhardt, Paul V.
    Martinez, Manuel
    Rodriguez, Carlos
    INORGANIC CHEMISTRY, 2009, 48 (11) : 4787 - 4797
12345