Synthesis and structure of 2D copper(II) coordination polymer with 1,2,4-benzenetricarboxylic acid

被引：0
|
作者：
Fan, J
Zhu, HF
Taka-Aki, O
Sun, WY [1 ]
Tang, WX
Norikazu, U
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 01期
关键词：
1,2,4-benzenetricarboxyhc acid; crystal structure; copper(II) complex; 2D structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer [Cu(HBTC)(H2O)(1).(5)].H2O (2) was synthesized by reaction of CuSO4.5H(2)O with a mononuclear complex [Mn(H2BTC)(2)(H2O)(4)].2H(2)O (1) which was obtained by the reaction of MnSO4.H2O with 1,2, 4- benzenetricarboxylic acid (H3BTC). The complexes 1 and 2 were characterized by X-ray crystallography. In complex 1, each Mn(II) atom is coordinated by two H2BTC- units and four water molecules; while in complex 2, each Cu(II) atom is coordinated by three HBTC2- units and two water molecules, one of which acts as a bridge, to generate an infinite 2D network.
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页码：17 / 20
页数：4
相关论文
共 26 条
  • [1] Baxter P. N. W., 1996, COMPREHENSIVE SUPRAM, V9
  • [2] BRZYSKA W, 1985, J THERM ANAL, P861
  • [3] The influence of the chelate effect on supramolecular structure formation: synthesis and crystal structures of zinc thiourea and and thiosemicarbazide complexes with terephthalate
    Burrows, AD
    Menzer, S
    Mingos, DMP
    White, AJP
    Williams, DJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22): : 4237 - 4240
  • [4] Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid
    Cao, R
    Sun, DF
    Liang, YC
    Hong, MC
    Tatsumi, K
    Shi, Q
    [J]. INORGANIC CHEMISTRY, 2002, 41 (08) : 2087 - 2094
  • [5] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores
    Chen, BL
    Eddaoudi, M
    Hyde, ST
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2001, 291 (5506) : 1021 - 1023
  • [6] Crystal structures of two- and three-dimensional polymeric complexes assembled by metal pseudohalides and 4-aminobenzoic acid via hydrogen bonds and covalent bonds
    Chen, HJ
    Chen, XM
    [J]. INORGANICA CHIMICA ACTA, 2002, 329 (01) : 13 - 21
  • [7] PREPARATION AND PROPERTIES OF THE TRIPLY BRIDGED, FERROMAGNETICALLY COUPLED DINUCLEAR COPPER(II) COMPLEXES [CU2(OAC)3(BPY)2](CLO4) AND [CU2(OH)(H2O)(OAC)(BPY)2](CLO4)2
    CHRISTOU, G
    PERLEPES, SP
    LIBBY, E
    FOLTING, K
    HUFFMAN, JC
    WEBB, RJ
    HENDRICKSON, DN
    [J]. INORGANIC CHEMISTRY, 1990, 29 (19) : 3657 - 3666
  • [8] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
    Chui, SSY
    Lo, SMF
    Charmant, JPH
    Orpen, AG
    Williams, ID
    [J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
  • [9] Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures
    Dai, JC
    Wu, XT
    Fu, ZY
    Cui, CP
    Hu, SM
    Du, WX
    Wu, LM
    Zhang, HH
    Sun, RO
    [J]. INORGANIC CHEMISTRY, 2002, 41 (06) : 1391 - 1396
  • [10] Observation of ferromagnetic and antiferromagnetic coupling in 1-D and 2-D extended structures of copper(II) terephthalates
    Deakin, L
    Arif, AM
    Miller, JS
    [J]. INORGANIC CHEMISTRY, 1999, 38 (22) : 5072 - 5077
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