Citric acid assisted solvothermal synthesis of BiFeO3 microspheres with high visible-light photocatalytic activity

被引：156
|
作者：
Huo, Yuning [1 ]
Jin, Yi [1 ]
Zhang, Ya [1 ]
机构：
[1] Shanghai Normal Univ, Dept Chem, Shanghai 200234, Peoples R China
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2010年 / 331卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
BiFeO3; photocatalyst; Solvothermal preparation; Citric acid; Visible light; Methylene blue (MB); HYDROTHERMAL SYNTHESIS; THIN-FILMS; TIO2; DECOMPOSITION; FABRICATION; PARTICLES; COMPLEXES; CE;
D O I：
10.1016/j.molcata.2010.08.009
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel BiFeO3 photocatalyst in the shape of uniform microspheres has been synthesized by solvothermal process assisted with chelating effect of citric acid. The higher photoactivity of this catalyst than that of BiFeO3 via solid-state reaction for methylene blue (MB) degradation under visible-light irradiation is owing to the high crystallization of perovskite-type BiFeO3, high surface area with hollow structure, narrow band gap energy of 2.1 eV, and the promotion of separation of photo-induced electrons and holes. Additionally, no decrease of activity after being reused repetitively for five times is indicative of the high hydrothermal stability of BiFeO3 particles without crystal phase transformation. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：15 / 20
页数：6
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