Suzuki-Miyaura cross-coupling of benzylic carbonates with arylboronic acids

被引:116
|
作者
Kuwano, R [1 ]
Yokogi, M [1 ]
机构
[1] Kyushu Univ, Grad Sch Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan
关键词
D O I
10.1021/ol050078q
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from [Pd(eta(3)-C3H5)Cl](2) and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes.
引用
收藏
页码:945 / 947
页数:3
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