Homogeneous Helical Nanofibers of 12-Hydroxystearic Acid and Long-chain Amidoamine Derivatives Prepared by Tuning the Gelation Solvent

被引:2
|
作者
Minakawa, Muneharu [1 ]
Nakagawa, Makoto [1 ]
Wang, Ke-Hsuan [1 ]
Imura, Yoshiro [1 ]
Kawai, Takeshi [1 ]
机构
[1] Tokyo Univ Sci, Shinjuku Ku, 1-3 Kagurazaka, Tokyo 1628601, Japan
关键词
Chiral supramolecular nanofiber; Gels; 12-Hydroxystearic acid; SUPRAMOLECULAR HYDROGELS; TEMPERATURE; TRANSITION;
D O I
10.1246/cl.200878
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We previously showed that the hybridization of water-insoluble 12-hydroxystearic acid (HSA) with water-soluble long-chain amidoamine derivatives yields hydrogels composed of self-assembled helical nanofibers. In this work, we investigated the effect of introducing an amide group into the alkyl chain of amidoamine derivatives on the helical structure of the nanofibers. We also demonstrated that improving the solubility of HSA by changing the gelation solvent is a very effective method for preparing homogeneous nanofibers composed of two compounds.
引用
收藏
页码:788 / 791
页数:4
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