Bridged Heterocyclium Dicationic closo-Icosahedral Perfluoroborane, Borane, and Carborane Salts via Aqueous, Open-Air Benchtop Synthesis

被引：12

作者：

Shackelford, Scott A.

Belletire, John L. ^{[3
]}

Boatz, Jerry A.

Schneider, Stefan

Wheaton, Amanda K. ^{[3
]}

Wight, Brett A. ^{[3
]}

Ammon, Herman L. ^{[1
]}

Peryshkov, Dmitry V. ^{[2
]}

Strauss, Steven H. ^{[2
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

[2] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

[3] USA, Res Lab, Propellants Branch AFRL RZSP, ERC Inc, Edwards AFB, CA 93524 USA

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 12期

关键词：

D O I：

10.1021/ol100752y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thirteen bridged triazolium and imidazolium dicationic salts, which uniquely pair closo-icosahedral perfluoroborane [B(12)F(12)](2-), borane [B(12)H(12)](2-), or carborane [CB(11)H(12)](-) anionic species with unsaturated bridged heterocyclium dications, were synthesized using an aqueous benchtop method. This considerably extends the scope of a reported aqueous synthesis of binary [heterocyclium](2)[B(12)H(12)] and [heterocyclium][CB(11)H(12)] salts. Also, the one-step preparation of five new precursor bridged heterocyclium dicationic dihalide salts using conventional procedures and in one case a microwave-assisted method Is described.

引用

页码：2714 / 2717

页数：4

共 3 条

[1] Bridged Heterocyclium Dicationic closo-Icosahedral Perfluoroborane, Borane, and Carborane Salts via Aqueous, Open-Air Benchtop Synthesis (vol 12, pg 2714, 2010)
Shackelford, Scott A.
Belletire, John L.
Boatz, Jerry A.
Schneider, Stefan
Wheaton, Amanda K.
Wight, Brett A.
Ammon, Herman L.
Peryshkov, Dmitry V.
Strauss, Steven H.
ORGANIC LETTERS, 2011, 13 (10) : 2795 - 2796
[2] Pairing Heterocyclic Cations with closo-Icosahedral Borane and Carborane Anions. I. Benchtop Aqueous Synthesis of Binary Triazolium and Imidazolium Salts with Limited Water Solubility
Shackelford, Scott A.
Belletire, John L.
Boatz, Jerry A.
Schneider, Stefan
Wheaton, Amanda K.
Wight, Brett A.
Hudgens, Leslie M.
Ammon, Herman L.
Strauss, Steven H.
ORGANIC LETTERS, 2009, 11 (12) : 2623 - 2626
[3] PAIRING HETEROCYCLIC CATIONS WITH CLOSO-ICOSAHEDRAL BORANE AND CARBORANE ANIONS, II: BENCHTOP ALTERNATIVE SYNTHETIC METHODOLOGIES FOR BINARY TRIAZOLIUM AND TETRAZOLIUM SALTS WITH SIGNIFICANT WATER SOLUBILITY
Belletire, John L.
Schneider, Stefan
Wight, Brett A.
Strauss, Steven L.
Shackelford, Scott A.
SYNTHETIC COMMUNICATIONS, 2012, 42 (02) : 155 - 169

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