Collaborative Interaction of Carbon-Carbon Unsaturated Bond Groups with Transition-metal Catalysts for C-H Bond Functionalization

被引：18
|
作者：
Minami, Yasunori [1 ]
Hiyama, Tamejiro [1 ]
机构：
[1] Chuo Univ, Res & Dev Initiat, Bunkyo Ku, 1-13-27 Kasuga, Tokyo 1128551, Japan
来源：
CHEMISTRY LETTERS | 2018年 / 47卷 / 01期
关键词：
C-H bond activation; Metal catalyst; Carbon-carbon unsaturated bond; ALKYNYL ARYL ETHERS; GAS SHIFT CONDITIONS; SILYLETHYNYL ETHERS; SELECTIVE SYNTHESIS; INTERNAL ALKYNES; ACTIVATION; ANNULATION; CYCLOADDITION; CYCLOCARBONYLATION; CLEAVAGE;
D O I：
10.1246/cl.170795
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkynes, alkenes, and thiophenes are found to behave as a directing group for C-H bond activation by a transition-metal catalyst. This collaborative interaction led to the discovery of not only simple intramolecular cyclizations but also carbon-carbon bond formation or annulation reactions with other reactants involving such unsaturated bond-directing groups. This highlight review discusses the recent progress in this sort of novel synthetic tools.
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页码：1 / 8
页数：8
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