Hierarchical Layer Engineering Using Supramolecular Double-Comb Diblock Copolymers

被引：20
|
作者：
Hofman, Anton H. [1 ]
Reza, Mehedi [2 ]
Ruokolainen, Janne [2 ]
ten Brinke, Gerrit [1 ]
Loos, Katja [1 ]
机构：
[1] Univ Groningen, Zernike Inst Adv Mat, Macromol Chem & New Polymer Mat, Nijenborgh 4, NL-9747 AG Groningen, Netherlands
[2] Aalto Univ, Dept Appl Phys, POB 11100, FI-00076 Aalto, Finland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 42期
关键词：
block copolymers; morphology; supramolecular self-assembly; NANOCOMPOSITE THIN-FILMS; POLYMERIC MATERIALS; MOLECULAR-WEIGHT; LENGTH SCALES; MORPHOLOGIES; TEMPERATURE; ASSEMBLIES; TRANSITION; TEMPLATES; SYSTEMS;
D O I：
10.1002/anie.201606890
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The formation of unusual multilayered parallel lamellae-in-lamellae in symmetric supramolecular double-comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block copolymer. The number of internal structures n was established to scale as M-0.67 and therefore enables easy design of such structures with great precision.
引用
收藏
页码：13081 / 13085
页数：5
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