HALOGEN-BONDED SUPRAMOLECULAR ARCHITECTURES INVOLVING 2,7-DIPYRIDYLFLUORENE AND 1,3,5-TRIFLUORO-2,4,6-TRIIODOBENZENE TECTONS - A SPECTACULAR EVOLUTION FROM CATEMERS TO 2D HALOGEN BOND ORGANIC FRAMEWORKS (XBOF)

被引:0
|
作者
Cata, Lidia [1 ,2 ]
Grosu, Ioana Georgeta [3 ]
Miclaus, Maria [3 ]
Hadade, Niculina Daniela [1 ,2 ]
Grosu, Ion [1 ,2 ]
Terec, Anamaria [1 ,2 ]
机构
[1] Babes Bolyai Univ, Fac Chem & Chem Engn, Dept Chem, 11 Arany Janos, Cluj Napoca 400028, Romania
[2] SOOMCC, 11 Arany Janos, Cluj Napoca 400028, Romania
[3] Natl Inst Res & Dev Isotop & Mol Technol, 67-103 Donath Str, Cluj Napoca 400293, Romania
来源
关键词
N???I and I???F halogen bonds; XBOFs; dipyridylfluorene; 1; 3; 5-trifluoro-2; 4; 6-triiodobenzene; single crystal X-ray diffraction structure; ASSEMBLIES; BRIDGES; UNITS;
D O I
10.24193/subbchem.2022.2.12
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A spectacular 2D Halogen Bond Organic Framework (XBOF) was prepared by the mechanochemical solvent-drop grinding method (SCD) starting from 2,7-dipyridylfluorene and 1,3,5-trifluoro-2,4,6-triiodobenzene tectons. The formation of the supramolecular assembly was proved by powder X-ray diffraction measurements and the structural details were collected from the single crystal X-ray diffraction investigations.
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页码:193 / 203
页数:11
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