InCl3-promoted allylation of aldehydes in ionic liquid:: Scope and enantioselectivity studies

被引：25
|
作者：
Lu, J
Ji, SJ [1 ]
Qian, R
Chen, JP
Liu, Y
Loh, TP
机构：
[1] Suzhou Univ, Coll Chem & Chem Engn, Suzhou 215006, Peoples R China
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
SYNLETT | 2004年 / 03期
关键词：
indium trichloride; allylation; aldehydes; catalyst; ionic liquid;
D O I：
10.1055/s-2004-815433
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Indium trichloride was successfully applied to allylation reaction of aldehydes using allytributyltin in ionic liquids. This accelerated catalytic system afforded the allylated products of various aldehydes in moderate to high yields. Preliminary studies on the enantioselectivity of this type of reaction have resulted in low to moderate enantioselectivities.
引用
收藏
页码：534 / 536
页数：3
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