Comment on "Algebraic perturbation theory for polar fluids: A model for the dielectric constant"

被引:22
|
作者
Szalai, I
Chan, KY
Henderson, D
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
[3] Univ Veszprem, Dept Phys Chem, H-8201 Veszprem, Hungary
来源
PHYSICAL REVIEW E | 2000年 / 62卷 / 06期
关键词
D O I
10.1103/PhysRevE.62.8846
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Kalikmanov [Phys. Rev. E 59, 4085 (1999)] proposed a perturbation theory method to calculate the dielectric constant of dipolar hard sphere fluids using an infinitely long cylindrical container to avoid the depolarization. We demonstrate that while the method is very helpful, his theory appears to be incomplete because of the incorrect calculation of the corresponding three-body integrals. It is shown that with the correct consideration of these terms the theory is consistent with the results of earlier work in low-density limit, and at high densities the method yields the equation of Tani et al. [Mol. Phys. 48, 863 (1983)] for the dipolar hard sphere fluid dielectric constant.
引用
收藏
页码:8846 / 8850
页数:5
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