Electron paramagnetic resonance of gamma-irradiated single crystals of 3-nitroacetanilide

被引:8
|
作者
Asik, Biray [1 ]
机构
[1] Kirikkale Univ, Dept Phys, Yahsihan, Kirikkale, Turkey
关键词
EPR; 3-nitroacetanilide; radicals; spin density;
D O I
10.1016/j.radphyschem.2008.02.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electron paramagnetic resonance of single crystals of 3-nitroacetanilide has been observed and analyzed for different orientations of the crystal in the magnetic field, after being damaged at 300 K by gamma-irradiation. The crystals have been investigated between 123 and 300 K. The spectra were found to be temperature independent. The irradiation of 3-nitroacetanilide by gamma-rays produces radicals at the nitrogen atoms in the molecule. The principal values of the hyperfine coupling tensor of the unpaired electron and the principal values of the g-tensor were determined. (C) 2008 Elsevier Ltd. All rights reserved.
引用
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页码:697 / 701
页数:5
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