Design and characterization of novel conductive nanocomposites based on carbon nanotube modified liquid crystalline epoxy

被引:0
|
作者
Shen, Tengfei [1 ,2 ,3 ]
Gao, Lihua [1 ]
Wu, Fachao [1 ]
Lu, Mangeng [2 ]
机构
[1] North China Inst Sci & Technol, Dept Environm Engn, Yanjiao Beijing 101601, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Dept Chem & Chem Engn, Beijing 10049, Peoples R China
关键词
multiwalled carbon nanotube; liquid crystalline epoxy; morphology; thermal properties; conductive adhesive; CURING REACTION; COMPOSITES; THERMOSETS; BEHAVIOR; ADHESIVES; NETWORKS; RESINS;
D O I
10.1080/15685551.2015.1012620
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work, a series of novel isotropically conductive adhesives (ICAs) based on multiwalled carbon nanotube (MWCNT)-modified liquid crystalline epoxy (LCE) resin was prepared. Different loadings of MWCNTs were used to produce LCE composites. Transmission electron microscope, scanning electron microscope, differential scanning calorimetry, polarized light optical microscopy, X-ray diffraction, electrical conductivity measurement, and tensile and flexural measurements were used to characterize the morphology, thermal, phase change, electrical, and mechanical properties of the prepared composites. The results showed that the added MWCNTs were dispersed well in the LCE matrix. The introducing MWCNTs did not show any major influence on typical curing peaks of LCE. Electrical conductivity at room temperature of the composites was increased significantly compared with neat LCE. The conductivity value of 10(-2)Scm(-1) was obtained at a weight concentration of only 0.5% MWCNT. In addition, tensile strength, Young's modulus, flexural strength, and flexural modulus of the composites were increased clearly compared with neat LCE matrix. These produced LCE composites with very low MWCNT loadings showed a great prospect of being used as ICAs.
引用
收藏
页码:323 / 332
页数:10
相关论文
共 50 条
  • [1] Carbon nanotubes modified nanocomposites based on liquid crystalline elastomers
    Wang, Qiao-E
    Niu, Hongyan
    Wang, Yawu
    Li, Chensha
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2022, 732 (01) : 11 - 49
  • [2] Kinetics Studies on the Accelerated Curing of Liquid Crystalline Epoxy Resin/Multiwalled Carbon Nanotube Nanocomposites
    Chen, Sharon
    Hsu, Sheng-Hao
    Wu, Ming-Chung
    Su, Wei Fang
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2011, 49 (04) : 301 - 309
  • [3] Synthesis and characterization of thermotropic liquid crystalline polyester/multi-walled carbon nanotube nanocomposites
    Wang, Xiaoyu
    Wang, Juanjuan
    Zhao, Wenfeng
    Zhang, Linwei
    Zhong, Xing
    Li, Rong
    Ma, Jiantai
    APPLIED SURFACE SCIENCE, 2010, 256 (06) : 1739 - 1743
  • [4] SYNTHESIS AND CHARACTERIZATION OF THERMOTROPIC LIQUID CRYSTALLINE POLYESTER/MULTI-WALLED CARBON NANOTUBE NANOCOMPOSITES
    Wang, J. J.
    Zhao, W. F.
    He, J. G.
    Dong, Z. P.
    Li, R.
    NANO, 2009, 4 (06) : 339 - 344
  • [5] High temperature liquid crystalline phase of polypropylene carbon nanotube nanocomposites
    Judith, Robert
    Georgiev, Georgi Y.
    Cabrera, Yaniel
    Wielgus, Lauren
    Cebe, Peggy
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [6] Influence of temperature on tensile behavior of multiwalled carbon nanotube modified epoxy nanocomposites
    Revathi, Aroor
    Rao, Sandhya
    Rao, Kavitha V.
    Prakash, Myadam Rajendra
    Murugan, Mohanraj Sendil
    Srihari, Shylaja
    Dayananda, Gidnahalli Narayana Reddy
    JOURNAL OF MATERIALS RESEARCH, 2014, 29 (15) : 1635 - 1641
  • [7] Influence of temperature on tensile behavior of multiwalled carbon nanotube modified epoxy nanocomposites
    Aroor Revathi
    Sandhya Rao
    Kavitha V. Rao
    Myadam Rajendra Prakash
    Mohanraj Sendil Murugan
    Shylaja Srihari
    Gidnahalli Narayana Reddy Dayananda
    Journal of Materials Research, 2014, 29 : 1635 - 1641
  • [8] Fabrication and performance improvement of liquid crystalline epoxy/carbon nanotube composite by surface treatment of carbon nanotube.
    Jang, J
    Bae, J
    Yoon, SH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U498 - U498
  • [9] A liquid-like multiwalled carbon nanotube derivative and its epoxy nanocomposites
    Wu, Fei
    Zheng, Yaping
    Qu, Ping
    Wang, Nan
    Chen, Lixin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 130 (03) : 2217 - 2224
  • [10] Reversible infrared actuation of carbon nanotube-liquid crystalline elastomer nanocomposites
    Yang, Liqiang
    Setyowati, Kristina
    Li, An
    Gong, Shaoqin
    Chen, Jian
    ADVANCED MATERIALS, 2008, 20 (12) : 2271 - +