Corresponding states theory for the prediction of surface tension of ionic liquids

被引:40
|
作者
Mousazadeh, M. H. [1 ]
Faramarzi, E. [2 ]
机构
[1] NSTRI, Nucl Sci Res Sch, Dept Chem, Tehran 113653486, Iran
[2] Univ Tehran, Sch Chem, Dept Phys Chem, Tehran, Iran
关键词
Corresponding states; Ionic liquids; Surface tension; PHYSICAL-PROPERTIES; PHASE-EQUILIBRIA; TEMPERATURE; DENSITY; BINARY; BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; PRINCIPLE; MIXTURES; EICOSANE; ANION;
D O I
10.1007/s11581-011-0536-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The surface tension of ionic liquids is studied according to phenomenological scaling and the law of corresponding states. The reduced coordinates gamma*-T*, where gamma* represents the reduced surface tension and T* is the reduced temperature, are introduced for the prediction of the surface tension from the melting point up to boiling point. It has been shown that the correlation can be expressed as a unique straight-line plot with a linear correlation coefficient of 0.984 that requires only the melting and boiling point parameters and can predict the surface tension accurately.
引用
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页码:217 / 222
页数:6
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