Synthesis of mono-coordinate iron(II)-phen complex via a solid state ligand exchange process from iron(II) oxalate dihydrate at room temperature under mechanical stressing

被引：3

作者：

Ohshita, T ^{[1
]}

Hirose, K ^{[1
]}

Komai, M ^{[1
]}

Senna, M ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2005年 / 35卷 / 05期

关键词：

iron(II) complex; ligand field distortion; mechanical stressing; solid state ligand exchange; spin crossover;

D O I：

10.1081/SIM-200059196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mono-coordinate iron(II)-1,10-phenanthroline (phen) complex was obtained in a solid state ligand exchange reaction under mechanical stressing by starting from a mixture of iron( II) oxalate dihydrate (FeC2O4 center dot 2H(2)O) and phen, which was not available via a thermal route or from iron( II) chloride tetra hydrate (FeCl2 center dot 4H(2)O).

引用

页码：355 / 358

页数：4

共 6 条

[1] Synthesis and Single-crystal Structures of Two Copper(II) Complexes and One Iron(II) Complex Prepared by in situ Ligand Substitution at Room Temperature
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[6] Role of molecular strain on the solid-state synthesis of coordination compounds from iron(II) chloride tetrahydrate and 1,10-phenanthroline under mechanical stress
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