Synthesis and structure of complex Ni(DPBP-SAH)2 • 2CH3CH2OH

被引：0
|
作者：
Zhang, L
Liu, L
Liu, GF
Jia, DZ [1 ]
Yu, KB
机构：
[1] Xinjiang Univ, Inst Appl Chem, Urumqi 830046, Xinjiang, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610012, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 21卷 / 02期
关键词：
crystal structure; nickel(II) complex; pyrazolone;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A nickel(II) complex Ni(DPBP-SAH)(2).2CH(3)CH(2)OH, (DPBP-SAH=N-(1,3-diphenyl-4-benzyllilene-5-pyrazolone)-salicylidene hydrazone), has been synthesized and characterized by elemental analyses, IR spectra and single crystal X-ray diffraction. It belongs to monoclinic, space group C2/c with a=2.737 9(4) nm, b=1249 2(2) nm, c=1.760 8(2) run, beta=120.212(9)degrees, M-iota=1 065.84, V=5.204(l) nm(3), Z=4. The X-ray diffraction reveals that the nickel (11) ion in the title complex is in a slightly distorted octahedral arrangement of the ON donor atoms of two DPBP-SAH and two O-donor atoms in ethanol.
引用
收藏
页码：291 / 294
页数：4
相关论文
共 21 条
  • [1] Synthesis of functionalised pyrazolones and imidazolines/imidazoles through divergent cyclisation reactions
    Abbiati, G
    Arcadi, A
    Attanasi, OA
    De Crescentini, L
    Rossi, E
    [J]. TETRAHEDRON, 2001, 57 (10) : 2031 - 2038
  • [2] ADAMS H, 2000, INORG CHEM COMMUN, V3, P4
  • [3] Synthesis and spectroscopic characterisation of copper(II) complexes with 5-methyl-1-(2′-pyridyl) pyrazole-3-carboxamide (MPyPzCA):: X-ray crystal structure of [Cu(MPyPzCA)2(H2O)](ClO4)2
    Adhikari, N
    Chaudhuri, S
    Butcher, RJ
    Saha, N
    [J]. POLYHEDRON, 1999, 18 (8-9) : 1323 - 1328
  • [4] Spectroscopic studies of the keto and enol tautomers of 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone
    Akama, Y
    Tong, AJ
    [J]. MICROCHEMICAL JOURNAL, 1996, 53 (01) : 34 - 41
  • [5] Raman spectroscopic study on keto-enol tautomers of 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone
    Akama, Y
    Tong, A
    Matsumoto, N
    Ikeda, T
    Tanaka, S
    [J]. VIBRATIONAL SPECTROSCOPY, 1996, 13 (01) : 113 - 115
  • [6] Synthesis, spectroscopic and cyclic voltammetry studies of copper(II) complexes with open chain, cyclic and a new macrocyclic thiosemicarbazones
    Franco, E
    López-Torres, E
    Mendiola, MA
    Sevilla, MT
    [J]. POLYHEDRON, 2000, 19 (04) : 441 - 451
  • [7] HAVANUR GH, 1987, INDIAN J CHEM A, V26, P1063
  • [8] COORDINATION-COMPOUNDS OF HYDRAZINE DERIVATIVES WITH TRANSITION-METALS .12. NICKEL(II) AND COPPER(II) CHELATES OF BIS(N-SALICYLIDENE)DICARBOXYLIC ACID DIHYDRAZIDES
    ISKANDER, MF
    ELSAYED, L
    HEFNY, AFM
    ZAYAN, SE
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1976, 38 (12): : 2209 - 2216
  • [9] Ji YL, 2003, CHINESE J INORG CHEM, V19, P345
  • [10] Ab initio study of structure, protonation and complex formation of novel pyrazolone-5 derivatives
    Kuznetsov, ML
    Dement'ev, AI
    Zhornik, VV
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2001, 571 : 45 - 57
123