Formation of tetra-chlorinated dibenzo-p-dioxins and their thermal decomposition products from pyrolysis reactions of tri-chlorophenates

被引:0
|
作者
Hong, JK
Park, J
Kim, KJ
机构
[1] KOREA ADV INST SCI & TECHNOL,SEOUL,SOUTH KOREA
[2] KOREA UNIV,DEPT CHEM,SEOUL 136701,SOUTH KOREA
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tetra-chlorodibenzo-p-dioxins (tetra-CDDs) were prepared by microscale pyrolysis of trichlorophenates. During the pyrolysis reaction, tri-, di-, and mono-CDDs were also formed by the thermolysis of tetra-CDDs. The dechlorination pathways of tetra-CDDs were suggested for this reaction. The identification of these products was performed with capillary column gas chromatography-mass spectrometry.
引用
收藏
页码:334 / 338
页数:5
相关论文
共 50 条
  • [1] A molecular recognition strategy towards tetra-chlorinated dibenzo-p-dioxins, TCDDs
    Hosoya, K
    Watabe, Y
    Ikegami, T
    Tanaka, N
    Kubo, T
    Sano, T
    Kaya, K
    BIOSENSORS & BIOELECTRONICS, 2004, 20 (06): : 1185 - 1189
  • [2] Formation of polychlorinated dibenzo-p-dioxins and dibenzofurans from chlorinated soot
    Addink, R
    Altwicker, RE
    CARBON, 2004, 42 (12-13) : 2661 - 2668
  • [3] Patterns of isomers of chlorinated dibenzo-p-dioxins as tool for elucidation of thermal formation mechanisms
    Wehrmeier, A
    Lenoir, D
    Schramm, KW
    Zimmermann, R
    Hahn, K
    Henkelmann, B
    Kettrup, A
    CHEMOSPHERE, 1998, 36 (13) : 2775 - 2801
  • [5] Kinetics of OH radical reactions with dibenzo-p-dioxin and selected chlorinated dibenzo-p-dioxins
    Taylor, PH
    Yamada, T
    Neuforth, A
    CHEMOSPHERE, 2005, 58 (03) : 243 - 252
  • [6] Synthesis and analysis of mixed chlorinated-fluorinated dibenzo-p-dioxins and dibenzofurans and assessment of formation and occurrence of the fluorinated and chlorinated-fluorinated dibenzo-p-dioxins and dibenzofurans
    Weber, R
    Hagenmaier, H
    CHEMOSPHERE, 1997, 34 (01) : 13 - 28
  • [7] Formation of chlorinated dibenzo-p-dioxins and dibenzo furans during chlorination of aquatic humic substances
    Hemming, J.
    Holmbon, B.
    Larsson, B.
    Proceedings of European Symposium, 1991,
  • [8] Mechanisms for the formation of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) from chlorinated toluenes
    Rawadieh, Saleh
    Altarawneh, Mohammednoor
    Altarawneh, Ibrahem
    Al-Shaweesh, Mouath A.
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2014, 112 (02) : 321 - 333
  • [9] Mechanisms for the formation of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) from chlorinated toluenes
    Saleh Rawadieh
    Mohammednoor Altarawneh
    Ibrahem Altarawneh
    Mouath A. Al-Shaweesh
    Reaction Kinetics, Mechanisms and Catalysis, 2014, 112 : 321 - 333
  • [10] FORMATION OF OCTA-CHLORINATED DIBENZO-P-DIOXIN AND ITS THERMAL-DECOMPOSITION PRODUCTS FROM PYROLYSIS REACTION OF PENTACHLOROPHENATE
    HONG, J
    YOO, JS
    CHANG, YS
    PARK, J
    KIM, KJ
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1995, 16 (02) : 79 - 81