Third-Order Nonlinear Optical Behavior of 5,11,17,23-Tetracyano-25,26,27,28-Tetrahydroxycalix[4]arene: Ab-initio Quantum Mechanical Calculations

被引：0
|
作者：
Karakas, Ash [1 ]
Ayhan, Elif [1 ]
机构：
[1] Selcuk Univ, Fac Sci, Dept Phys, TR-42049 Campus, Konya, Turkey
来源：
2011 13TH INTERNATIONAL CONFERENCE ON TRANSPARENT OPTICAL NETWORKS (ICTON) | 2011年
关键词：
nonlinear optic; time-dependent Hartree-Fock; linear polarizability; second hyperpolarizability;
D O I：
暂无
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
A potential nonlinear optical (NLO) compound has been designed. To provide an insight into the microscopic NLO properties of the title molecule, both dispersion-free (static) and also frequency-dependent (dynamic) linear polarizabilities (alpha) and third-order hyperpolarizabilities (gamma) at lambda = 825 - 1125 nm and 1050 - 1600 nm wavelength areas have been computed using time-dependent Hartree-Fock (TDHF) method. The ab-initio quantum mechanical results on (hyper)polarizabilities show that the examined compound might have microscopic third-order NLO phenomena with non-zero values.
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页数：3
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