Synthesis and characterization of a thermally crosslinkable polyolefin from oleic acid

被引：6
|
作者：
Ohtake, Kazuhisa [1 ]
Onose, Yusuke [1 ]
Kuwabara, Junpei [1 ]
Kanbara, Takaki [1 ]
机构：
[1] Univ Tsukuba, Tsukuba Res Ctr Energy Mat Sci TREMS, Grad Sch Pure & Appl Sci, Tennodai 1-1-1, Tsukuba, Ibaraki 3058573, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2019年 / 57卷 / 02期
关键词：
adhesion; biopolymers; crosslinking; polyolefins; thermosets; FATTY-ACIDS; POLYMERIZATION; OLEFINS; FUNCTIONALIZATION; TRANSFORMATION; AUTOXIDATION; CATALYST; BEHAVIOR;
D O I：
10.1002/pola.29269
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel thermally crosslinkable polyolefin was synthesized from biorenewable oleic acid. The obtained polymer exhibited a unique structure, bearing an inner olefin moiety in the long side chain. Since thermal auto-oxidation and crosslinking reactions occurred at the inner olefin moiety of polymer, it could be cured by heating in air. The resultant polymer exhibited good adhesion properties to various substrates.
引用
收藏
页码：85 / 89
页数：5
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