Synthesis, heterogenization and sensing properties of melamine-bridged bis-porphyrin dimers

被引:4
|
作者
Carofiglio, Tommaso [1 ,2 ]
Lubian, Elisa [1 ,2 ]
Varotto, Alessandro [3 ]
机构
[1] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy
[2] Univ Padua, CNR, ITM, I-35131 Padua, Italy
[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
关键词
supported porphyrins; cyanuric chloride; optical sensors; biogenic diamines; COLORIMETRIC SENSOR ARRAYS; MOLECULAR RECOGNITION; ZINC PORPHYRINS; RECEPTOR; HOST; BASE; COMPLEXATION; DERIVATIVES; FULLERENES; DENDRIMERS;
D O I
10.1142/S1088424610002550
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A straightforward, "one-pot" approach to the construction of a new class of molecular tweezers and their heterogenization onto various aminated materials is reviewed here. It is based on nucleophilic substitution of the cyanuric chloride scaffold with tailored aminoporphyrin subunits. The molecular recognition properties of these porphyrinic materials for diamine sensing are also discussed.
引用
收藏
页码:701 / 707
页数:7
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