Nickel-catalyzed allyl-allyl coupling reactions between 1,3-dienes and allylboronates

被引：14
|
作者：
Ji, Ding-Wei [1 ,2 ]
He, Gu-Cheng [1 ]
Zhang, Wei-Song [1 ]
Zhao, Chao-Yang [1 ]
Hu, Yan-Cheng [1 ]
Chen, Qing-An [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 54期
基金：
中国国家自然科学基金;
关键词：
DIENES; HYDROALLYLATION; HYDROAMINATION; CARBONATES; ALCOHOLS; AMINES;
D O I：
10.1039/d0cc02697b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A regiospecific allyl-allyl coupling reaction between 1,3-dienes and allylboronates has been demonstrated under nickel catalysis. Salient features of this method include the earth-abundant metal catalyst, excellent regioselectivity and good functional group tolerance. Notably, even congested allyl substrates can also be applied to this protocol, thus allowing for the rapid preparation of a series of valuable 1,5-dienes.
引用
收藏
页码：7431 / 7434
页数：4
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