Catalyst and additive-free oxidative dual C-H sulfenylation of imidazoheterocycles with elemental sulfur using DMSO as a solvent and an oxidant

被引：41

作者：

Guo, Tao ^{[1
]}

Wei, Xu-Ning ^{[1
]}

Zhang, Miao ^{[2
]}

Liu, Yu ^{[1
]}

Zhu, Li-Min ^{[1
]}

Zhao, Yun-Hui ^{[3
]}

机构：

[1] Henan Univ Technol, Sch Chem & Chem Engn, Zhengzhou 450001, Henan, Peoples R China

[2] Zhengzhou Univ, Dept Pharm, Childrens Hosp, Zhengzhou 450001, Henan, Peoples R China

[3] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Hunan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 43期

关键词：

ARYL; THIOLATION; CHALCOGENATION; SULFIDES; ACID; TRIFLUOROMETHYLTHIOLATION; IMIDAZOPYRIDINES; KETONES; POWDER; DIARYL;

D O I：

10.1039/d0cc00043d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dual C-H sulfenylation was used to obtain 3-vulcanized imidazoheterocycles using odorless elemental sulfur under catalyst- and additive-free conditions. C-H activation of both imidazoheterocycles and arylamines/arenols/indoles was realized by a practical protocol in which DMSO served as both a solvent and an internal oxidant.

引用

页码：5751 / 5754

页数：4

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